Ligand-Enabled γ-C–H Olefination and Carbonylation: Construction of β-Quaternary Carbon Centers

نویسندگان

  • Suhua Li
  • Gang Chen
  • Chen-Guo Feng
  • Wei Gong
  • Jin-Quan Yu
چکیده

Monoselective γ-C-H olefination and carbonylation of aliphatic acids has been accomplished by using a combination of a quinoline-based ligand and a weakly coordinating amide directing group. The reaction provides a new route for constructing richly functionalized all-carbon quaternary carbon centers at the β-position of aliphatic acids.

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عنوان ژورنال:

دوره 136  شماره 

صفحات  -

تاریخ انتشار 2014